- Draw the Lewis structure for H2O, CH4 (methane), and for NH3.
- Write the Lewis structure of the following molecules:
a. Ethylene, C2H4
b. Acetylene, C2H2
c. Carbon tetrachloride, CCl4
d. COBr2 (for the skeletal structure, C is bonded to O and Br atoms)
The Correct Answer and Explanation is :
Here are the Lewis structures for the given molecules, followed by a detailed explanation:
1. Lewis Structures
a. Water (H₂O):
- Central atom: Oxygen.
- Each hydrogen atom forms a single bond with oxygen.
- Oxygen has two lone pairs of electrons.
H
|
H—O
|
H
b. Methane (CH₄):
- Central atom: Carbon.
- Carbon forms single bonds with four hydrogen atoms.
- Carbon has no lone pairs.
H
|
H—C—H
|
H
c. Ammonia (NH₃):
- Central atom: Nitrogen.
- Nitrogen forms three single bonds with hydrogen atoms.
- Nitrogen has one lone pair of electrons.
H
|
H—N—H
..
2. Lewis Structures
a. Ethylene (C₂H₄):
- Each carbon atom forms a double bond with the other carbon and single bonds with two hydrogen atoms.
H H
\ /
C=C
/ \
H H
b. Acetylene (C₂H₂):
- Carbon atoms are triple-bonded to each other, with each carbon forming a single bond to one hydrogen atom.
H-C≡C-H
c. Carbon tetrachloride (CCl₄):
- Carbon forms single bonds with four chlorine atoms, each chlorine atom has three lone pairs.
Cl
|
Cl-C-Cl
|
Cl
d. COBr₂:
- Carbon is bonded to oxygen (double bond) and two bromine atoms (single bonds). Oxygen has two lone pairs, and bromine atoms each have three lone pairs.
Br
|
O=C
|
Br
Explanation (Approx. 300 Words)
The Lewis structure illustrates the arrangement of atoms, bonds, and lone pairs in a molecule. Electrons are shown as dots, while bonds are depicted as lines. Here’s a breakdown of the reasoning:
- Octet Rule: Atoms aim to complete their octet (8 valence electrons), except hydrogen, which requires only 2 electrons.
- Steps to Draw a Lewis Structure:
- Count total valence electrons for all atoms.
- Arrange atoms with the least electronegative atom (except hydrogen) in the center.
- Form single bonds, then add double/triple bonds as needed.
- Distribute lone pairs to satisfy the octet rule.
- Key Insights:
- Water (H₂O): Oxygen has 6 valence electrons, shares 2 electrons with hydrogens, and retains 2 lone pairs.
- Methane (CH₄): Carbon shares its 4 valence electrons equally with hydrogen atoms.
- Ammonia (NH₃): Nitrogen shares 3 electrons with hydrogens, leaving 1 lone pair.
- Ethylene (C₂H₄): A double bond between carbons satisfies their octets while hydrogens form single bonds.
- Acetylene (C₂H₂): A triple bond between carbons ensures octet fulfillment; each carbon also bonds to one hydrogen.
- Carbon tetrachloride (CCl₄): Carbon forms single bonds with four chlorine atoms, completing all octets.
- COBr₂: The skeletal structure places oxygen (double bond) and bromine (single bonds) around carbon, adhering to the octet rule.