Below is the IR spectrum for isoamyl acetate (banana oil). Which peaks correspond to functional groups present in isoamyl acetate?

The Correct Answer and Explanation is :
Isoamyl acetate, commonly known as banana oil, is an ester with the chemical formula C₇H₁₄O₂. Its infrared (IR) spectrum reveals several characteristic peaks corresponding to specific functional groups:
- Carbonyl Stretching (C=O): A strong absorption band near 1740 cm⁻¹ indicates the presence of the ester carbonyl group. This peak is typical for esters and is a key feature in their IR spectra. citeturn0search0
- C-H Stretching: Bands around 2960 cm⁻¹ correspond to C-H stretching vibrations of alkyl groups. These are common in organic compounds containing alkyl chains. citeturn0search0
- C-H Bending: A band near 1370 cm⁻¹ is associated with C-H bending vibrations, further confirming the presence of alkyl groups. citeturn0search0
- C-O Stretching: A medium-intensity band around 1240 cm⁻¹ corresponds to C-O stretching vibrations, characteristic of ester linkages. citeturn0search0
These peaks collectively confirm the ester functional group in isoamyl acetate. The strong C=O stretching band near 1740 cm⁻¹ is particularly indicative of ester compounds. citeturn0search1
In summary, the IR spectrum of isoamyl acetate exhibits characteristic peaks that correspond to the ester functional group, including the C=O stretching, C-H stretching and bending, and C-O stretching vibrations. These features are essential for identifying and confirming the presence of isoamyl acetate in a sample.