Assign following salts acid/base/neutral
a) KNO3
b) K2SO4
C) K2S
D) NH4NO3
E) NaHSO4
F) NaHCO3
G) NaH2PO4
The correct answer and explanation is :
To determine whether a salt is acidic, basic, or neutral, we need to look at the parent acids and bases from which the salt is derived. The following guidelines can help:
- Neutral salts are formed from strong acids and strong bases (e.g., NaCl from HCl and NaOH).
- Acidic salts are formed from a strong acid and a weak base (e.g., NH4Cl from HCl and NH3).
- Basic salts are formed from a weak acid and a strong base (e.g., Na2CO3 from H2CO3 and NaOH).
Now let’s analyze each of the salts you listed:
a) KNO3 (Potassium Nitrate):
- KNO3 is formed from KOH (strong base) and HNO3 (strong acid).
- Since both the acid and the base are strong, the salt is neutral.
b) K2SO4 (Potassium Sulfate):
- K2SO4 is formed from KOH (strong base) and H2SO4 (strong acid).
- As both the acid and the base are strong, the salt is neutral.
c) K2S (Potassium Sulfide):
- K2S is formed from KOH (strong base) and H2S (weak acid).
- The conjugate base of H2S (which is S²⁻) is strong enough to accept protons, making the solution basic. Thus, K2S is basic.
d) NH4NO3 (Ammonium Nitrate):
- NH4NO3 is formed from NH3 (weak base) and HNO3 (strong acid).
- Since the acid is strong and the base is weak, the salt dissociates to produce NH4⁺, which is a weak acid. Therefore, NH4NO3 is acidic.
e) NaHSO4 (Sodium Bisulfate):
- NaHSO4 is formed from NaOH (strong base) and H2SO4 (strong acid), where only one hydrogen remains in the bisulfate ion (HSO4⁻).
- The HSO4⁻ ion can act as a weak acid (it can donate a proton), so the salt is acidic.
f) NaHCO3 (Sodium Bicarbonate):
- NaHCO3 is formed from NaOH (strong base) and H2CO3 (weak acid).
- The HCO3⁻ ion acts as a weak base, making the salt basic.
g) NaH2PO4 (Sodium Dihydrogen Phosphate):
- NaH2PO4 is formed from NaOH (strong base) and H3PO4 (weak acid).
- The H2PO4⁻ ion is weakly acidic, so this salt will be acidic.
Summary:
- Neutral: KNO3, K2SO4
- Basic: K2S, NaHCO3
- Acidic: NH4NO3, NaHSO4, NaH2PO4