Saved Which of the following Lewis structures are INCORRECT? 1) BrF3 Br 2) COCl2 C-C-C: 3) HCN H-C=N: 4) HFCO E-C-# 1

Saved Which of the following Lewis structures are INCORRECT? 1) BrF3 Br 2) COCl2 C-C-C: 3) HCN H-C=N: 4) HFCO E-C-# 1

The Correct Answer and Explanation is:

The question asks which Lewis structures are incorrect, and the correct answer is:

2) COCl₂ and 4) HFCOboth are incorrect.


Explanation

1) BrF₃ (Bromine trifluoride)Correct

The Lewis structure for BrF₃ is accurate. Bromine (Br) is the central atom with 3 bonded fluorine atoms and 2 lone pairs. This leads to 5 electron regions, which gives it a T-shaped molecular geometry, matching the Lewis structure shown.


2) COCl₂ (Phosgene)Incorrect

The shown structure has two carbon atoms, which is incorrect. COCl₂ should have one central carbon atom double-bonded to one oxygen atom and single-bonded to two chlorine atoms. The correct Lewis structure is:

mathematicaCopyEdit     O
     ||
Cl—C—Cl
  • Carbon has 4 bonds (full octet).
  • Oxygen has a double bond and two lone pairs.
  • Chlorines have three lone pairs each.

The structure in the image incorrectly shows C–C–C bonding, which does not represent phosgene. Therefore, it’s incorrect.


3) HCN (Hydrogen cyanide)Correct

The given Lewis structure for HCN is:

mathematicaCopyEditH—C≡N:
  • Hydrogen forms 1 bond.
  • Carbon forms 4 bonds (1 with H, 3 with N).
  • Nitrogen has a triple bond and one lone pair.

This is correct.


4) HFCO (Formyl fluoride)Incorrect

The image incorrectly shows a single bond between C and O and possibly incorrect bonding arrangements. The correct structure is:

scssCopyEditH—C(=O)—F
  • Carbon forms 4 bonds: 1 to H, 1 to F, and 2 to O (double bond).
  • Oxygen has 2 lone pairs.
  • Fluorine has 3 lone pairs.

The image structure appears to violate the octet rule and bonding conventions, so it’s incorrect.


Final Answer:

2 and 4 are incorrect Lewis structures.

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