Saved Which of the following Lewis structures are INCORRECT? 1) BrF3 Br 2) COCl2 C-C-C: 3) HCN H-C=N: 4) HFCO E-C-# 1

Saved Which of the following Lewis structures are INCORRECT? 1) BrF3 Br 2) COCl2 C-C-C: 3) HCN H-C=N: 4) HFCO E-C-# 1

The Correct Answer and Explanation is:

The question asks which Lewis structures are incorrect, and the correct answer is:

✅ 2) COCl₂ and 4) HFCO — both are incorrect.


Explanation

1) BrF₃ (Bromine trifluoride) – Correct

The Lewis structure for BrF₃ is accurate. Bromine (Br) is the central atom with 3 bonded fluorine atoms and 2 lone pairs. This leads to 5 electron regions, which gives it a T-shaped molecular geometry, matching the Lewis structure shown.


2) COCl₂ (Phosgene) – Incorrect

The shown structure has two carbon atoms, which is incorrect. COCl₂ should have one central carbon atom double-bonded to one oxygen atom and single-bonded to two chlorine atoms. The correct Lewis structure is:

mathematicaCopyEdit     O
     ||
Cl—C—Cl
  • Carbon has 4 bonds (full octet).
  • Oxygen has a double bond and two lone pairs.
  • Chlorines have three lone pairs each.

The structure in the image incorrectly shows C–C–C bonding, which does not represent phosgene. Therefore, it’s incorrect.


3) HCN (Hydrogen cyanide) – Correct

The given Lewis structure for HCN is:

mathematicaCopyEditH—C≡N:
  • Hydrogen forms 1 bond.
  • Carbon forms 4 bonds (1 with H, 3 with N).
  • Nitrogen has a triple bond and one lone pair.

This is correct.


4) HFCO (Formyl fluoride) – Incorrect

The image incorrectly shows a single bond between C and O and possibly incorrect bonding arrangements. The correct structure is:

scssCopyEditH—C(=O)—F
  • Carbon forms 4 bonds: 1 to H, 1 to F, and 2 to O (double bond).
  • Oxygen has 2 lone pairs.
  • Fluorine has 3 lone pairs.

The image structure appears to violate the octet rule and bonding conventions, so it’s incorrect.


Final Answer:

✅ 2 and 4 are incorrect Lewis structures.

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