Write the Lewis structure for each molecule. a. CH2O b. C2Cl4
The Correct Answer and Explanation is:
a. CH₂O (Formaldehyde)
Lewis Structure:
mathematicaCopyEdit H
|
H–C=O
||
O
Explanation:
Formaldehyde (CH₂O) consists of one carbon (C), two hydrogen (H), and one oxygen (O) atom. Here’s how we draw its Lewis structure:
- Count total valence electrons:
- Carbon (Group 14): 4 electrons
- Hydrogen (Group 1): 1 electron × 2 = 2 electrons
- Oxygen (Group 16): 6 electrons
- Total = 4 + 2 + 6 = 12 valence electrons
- Determine the central atom:
Carbon is the central atom because it can form 4 bonds, while H and O typically form 1 and 2 bonds respectively. - Create single bonds between C and H, and C and O:
- Each bond uses 2 electrons: 3 single bonds = 6 electrons used.
- Distribute remaining electrons:
- 6 electrons remain. Place them as lone pairs on oxygen.
- Check octet rule:
- Carbon has only 6 electrons; to complete its octet, form a double bond with oxygen.
- Final bonding: 2 single bonds (C–H), 1 double bond (C=O).
- Final structure: Carbon forms two single bonds with H and a double bond with O. Oxygen has two lone pairs, satisfying the octet rule.
b. C₂Cl₄ (Tetrachloroethylene)
Lewis Structure:
mathematicaCopyEdit Cl Cl
\ /
C = C
/ \
Cl Cl
Explanation:
Tetrachloroethylene has two carbon (C) atoms and four chlorine (Cl) atoms.
- Count total valence electrons:
- Carbon: 4 × 2 = 8 electrons
- Chlorine: 7 × 4 = 28 electrons
- Total = 36 valence electrons
- Determine structure:
- Carbon atoms form a double bond (C=C) in the center.
- Each carbon is also bonded to two chlorine atoms (4 single bonds total).
- Assign lone pairs:
- Chlorine atoms get 3 lone pairs each (6 electrons × 4 = 24 electrons).
- The double bond and single bonds account for 12 electrons (6 bonds × 2 electrons).
- Octet rule:
- Each atom satisfies the octet. Carbon atoms have 4 bonds each (8 electrons), chlorine has 1 bond and 3 lone pairs (also 8 electrons).
- Final structure: Two central carbon atoms form a double bond, each bonded to two chlorine atoms.
These Lewis structures illustrate correct electron pairing and bonding based on valence electron rules and the octet principle.
