A straight-chain organic compound containing an aldehyde functional group has a molecular formula of C5H11CHO. Draw the corresponding skeletal structure. C-H bonds are implied. Select to Draw
The correct answer and explanation is :
The molecular formula C₅H₁₁CHO represents a straight-chain aldehyde. Let’s break this down:
Step 1: Understanding the Structure
- The “CHO” functional group signifies the presence of an aldehyde (-C(=O)H) functional group.
- The remaining part, C₅H₁₁, suggests a pentyl (C₅H₁₁) group.
- Since it is a straight-chain compound, it means that the carbon atoms are connected in a single continuous chain without branching.
Step 2: Identifying the Parent Chain
- The longest carbon chain must include the aldehyde functional group.
- The parent chain here is hexanal (six carbon atoms including the aldehyde group).
Step 3: Drawing the Skeletal Structure
- In a skeletal structure:
- Carbon atoms are represented by the ends and vertices of lines.
- Hydrogen atoms attached to carbon are not explicitly shown (they are implied).
- The aldehyde group (-CHO) must be explicitly shown at the end of the chain.
Here’s the skeletal structure of hexanal:
O
||
CH3-CH2-CH2-CH2-CH2-C-H
Or in skeletal notation:
O
||
/\/\/C-H
(Each vertex represents a carbon, and the aldehyde functional group is at the terminal end.)
Step 4: Explanation
- The structure follows the molecular formula C₅H₁₁CHO.
- The aldehyde functional group (-CHO) is always at the end of the chain because aldehydes are terminal functional groups.
- The remaining five carbon atoms form a continuous straight chain.
- The molecular structure does not include branches, as per the given condition.
This compound is called hexanal, a simple aldehyde with six carbon atoms.