VSEPR theory

VSEPR theory? Seesaw B. T-shaped Bent or V-shaped D, Trigonal planar Tetrahedral
Question 2 What is the molecular geometry of IBr3 according to the VSEPR theory? Seesaw B. T-shaped Bent or V-shaped D, Trigonal planar Tetrahedra

The Correct Answer and Explanation is:

The correct answer is: B. T-shaped


Explanation:

To determine the molecular geometry of IBr₃ using VSEPR (Valence Shell Electron Pair Repulsion) theory, follow these steps:

Step 1: Determine the number of valence electrons

  • Iodine (I) is in group 17, so it has 7 valence electrons.
  • Each bromine (Br) also has 7 valence electrons, and there are 3 Br atoms.

However, for geometry, we focus on the central atom—Iodine.

Step 2: Bonding and lone pairs on iodine

  • Iodine forms three single bonds with each Br atom, using 3 of its 7 valence electrons.
  • This leaves 4 electrons, or 2 lone pairs (since each lone pair consists of 2 electrons).

So iodine in IBr₃ has:

  • 3 bonding pairs (Br atoms),
  • 2 lone pairs.

This results in a total of 5 regions of electron density.

Step 3: Use VSEPR to predict shape

With 5 electron regions, the electron geometry is trigonal bipyramidal. However, lone pairs occupy equatorial positions to minimize repulsion.

  • The 3 Br atoms occupy two axial and one equatorial position.
  • The 2 lone pairs occupy the remaining equatorial positions.

Step 4: Determine the molecular geometry

When a molecule has:

  • 3 bonding pairs,
  • 2 lone pairs,
  • in a trigonal bipyramidal electron geometry,

The molecular geometry is T-shaped.

Conclusion:

The lone pairs distort the ideal shape, and the three bonded atoms form a T-shaped structure. Hence, according to VSEPR theory, the molecular geometry of IBr₃ is T-shaped.

Correct answer: B. T-shaped

Scroll to Top