Question 25 2.5 pts What is the correct Lewis structure for oxygen difluoride molecule, OF

Question 25 2.5 pts What is the correct Lewis structure for oxygen difluoride molecule, OF
?
F::O::F
F::O::F
F::O::F
F::O::F
:F::O::F:

The Correct Answer and Explanation is:

ChatGPT said:

The correct Lewis structure for the oxygen difluoride (OF₂) molecule is the last option (fifth one):

:F–O–F:
Each fluorine (F) atom has three lone pairs, and the oxygen (O) atom has two lone pairs, with single bonds connecting O to each F atom.


Explanation

Oxygen difluoride (OF₂) consists of one oxygen atom bonded to two fluorine atoms. To determine the correct Lewis structure, follow these steps:


1. Count Valence Electrons:

  • Oxygen (O) has 6 valence electrons.
  • Fluorine (F) has 7 valence electrons, and there are two F atoms.
    Total valence electrons = 6 (O) + 7×2 (F) = 20 electrons

2. Determine Atom Placement:

Oxygen is less electronegative than fluorine, so it is the central atom, with the two fluorines bonded to it.


3. Create Single Bonds:

Create single bonds between O and each F:

  • 2 single bonds = 2×2 = 4 electrons used
  • Remaining electrons = 20 – 4 = 16 electrons

4. Distribute Remaining Electrons as Lone Pairs:

  • Each F needs 3 lone pairs (6 electrons), so 2 Fs = 12 electrons
  • 4 electrons remain, which go as 2 lone pairs on O

Now, each atom has a full octet:

  • Fluorines: 1 bond + 6 electrons = 8 electrons
  • Oxygen: 2 bonds + 4 electrons (2 lone pairs) = 8 electrons

5. Check Formal Charges:

All atoms have formal charges of zero. This confirms that this is the most stable structure.


6. Molecular Shape:

Though not required for the Lewis structure itself, it’s worth noting:
OF₂ has a bent shape due to the two lone pairs on oxygen (similar to H₂O), and the bond angle is slightly less than 109.5° due to lone pair repulsion.


Conclusion:

The correct Lewis structure is the one showing oxygen in the center, with two single bonds to fluorine atoms, and lone pairs properly distributed:
:F–O–F:

Scroll to Top