{"id":192976,"date":"2025-02-18T16:53:07","date_gmt":"2025-02-18T16:53:07","guid":{"rendered":"https:\/\/learnexams.com\/blog\/?p=192976"},"modified":"2025-02-18T16:53:16","modified_gmt":"2025-02-18T16:53:16","slug":"dinitrogen-monoxide-n%e2%82%82o-can-decompose-to-nitrogen-and-oxygen-gas","status":"publish","type":"post","link":"https:\/\/www.learnexams.com\/blog\/2025\/02\/18\/dinitrogen-monoxide-n%e2%82%82o-can-decompose-to-nitrogen-and-oxygen-gas\/","title":{"rendered":"Dinitrogen monoxide, N\u2082O, can decompose to nitrogen and oxygen gas"},"content":{"rendered":"\n<p>Dinitrogen monoxide, N\u2082O, can decompose to nitrogen and oxygen gas:<br>2 N2O(g) \u2192 2 N2(g) + O2(g)<br>Use bond dissociation enthalpies (see Table on last page) to estimate the enthalpy change for this reaction. (Hint: As in problem #6, first draw the Lewis structures of the reactants and products that obey the octet rule so you knov the types of bonds involved to determine their bond dissociation energies. N\u2082O has the following stable Lewis<br>structure: :N=N-0:<\/p>\n\n\n\n<p><mark style=\"background-color:rgba(0, 0, 0, 0)\" class=\"has-inline-color has-ast-global-color-6-color\"><strong>The Correct Answer and Explanation is :<\/strong><\/mark><\/p>\n\n\n\n<p>To estimate the enthalpy change for the decomposition of dinitrogen monoxide (N\u2082O) into nitrogen (N\u2082) and oxygen (O\u2082) using bond dissociation enthalpies, follow these steps:<\/p>\n\n\n\n<h3 class=\"wp-block-heading\">1. <strong>Write the balanced reaction:<\/strong><\/h3>\n\n\n\n<p>The decomposition of dinitrogen monoxide can be written as:<br>[<br>2 \\text{N}_2\\text{O}(g) \\rightarrow 2 \\text{N}_2(g) + \\text{O}_2(g)<br>]<\/p>\n\n\n\n<h3 class=\"wp-block-heading\">2. <strong>Draw the Lewis Structures:<\/strong><\/h3>\n\n\n\n<p>We will use the following Lewis structures for the molecules:<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li><strong>N\u2082O (dinitrogen monoxide)<\/strong>: The stable structure of N\u2082O is :N=N-O:, where:<\/li>\n\n\n\n<li>N-N bond: single bond (N-N)<\/li>\n\n\n\n<li>N-O bond: single bond (N-O)<\/li>\n\n\n\n<li><strong>N\u2082 (nitrogen)<\/strong>: Each nitrogen molecule has a triple bond between two nitrogen atoms:<\/li>\n\n\n\n<li>N\u2261N bond: triple bond (N\u2261N)<\/li>\n\n\n\n<li><strong>O\u2082 (oxygen)<\/strong>: Oxygen gas has a double bond between the two oxygen atoms:<\/li>\n\n\n\n<li>O=O bond: double bond (O=O)<\/li>\n<\/ul>\n\n\n\n<h3 class=\"wp-block-heading\">3. <strong>Bond Dissociation Enthalpies:<\/strong><\/h3>\n\n\n\n<p>To estimate the enthalpy change for the reaction, use bond dissociation enthalpies for each bond involved.<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li><strong>N\u2082O<\/strong> has:<\/li>\n\n\n\n<li>1 N-N bond: approximately 160 kJ\/mol<\/li>\n\n\n\n<li>1 N-O bond: approximately 200 kJ\/mol<\/li>\n\n\n\n<li><strong>N\u2082<\/strong> has:<\/li>\n\n\n\n<li>1 N\u2261N bond: approximately 945 kJ\/mol<\/li>\n\n\n\n<li><strong>O\u2082<\/strong> has:<\/li>\n\n\n\n<li>1 O=O bond: approximately 498 kJ\/mol<\/li>\n<\/ul>\n\n\n\n<h3 class=\"wp-block-heading\">4. <strong>Calculate the Enthalpy Change:<\/strong><\/h3>\n\n\n\n<p>To find the total enthalpy change, we need to consider both the bonds broken (reactants) and the bonds formed (products).<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li><strong>Bonds broken<\/strong>:<\/li>\n\n\n\n<li>2 N-N bonds (in two N\u2082O molecules): 2 \u00d7 160 kJ\/mol = 320 kJ\/mol<\/li>\n\n\n\n<li>2 N-O bonds (in two N\u2082O molecules): 2 \u00d7 200 kJ\/mol = 400 kJ\/mol<\/li>\n\n\n\n<li>Total energy to break bonds: 320 kJ\/mol + 400 kJ\/mol = 720 kJ\/mol<\/li>\n\n\n\n<li><strong>Bonds formed<\/strong>:<\/li>\n\n\n\n<li>2 N\u2261N bonds (in two N\u2082 molecules): 2 \u00d7 945 kJ\/mol = 1890 kJ\/mol<\/li>\n\n\n\n<li>1 O=O bond (in one O\u2082 molecule): 1 \u00d7 498 kJ\/mol = 498 kJ\/mol<\/li>\n\n\n\n<li>Total energy to form bonds: 1890 kJ\/mol + 498 kJ\/mol = 2388 kJ\/mol<\/li>\n<\/ul>\n\n\n\n<h3 class=\"wp-block-heading\">5. <strong>Enthalpy Change for the Reaction:<\/strong><\/h3>\n\n\n\n<p>The enthalpy change (\u0394H) can be calculated by subtracting the total energy required to break bonds from the energy released when new bonds are formed:<br>[<br>\\Delta H = \\text{Bonds formed} &#8211; \\text{Bonds broken}<br>]<br>[<br>\\Delta H = 2388 \\, \\text{kJ\/mol} &#8211; 720 \\, \\text{kJ\/mol} = 1668 \\, \\text{kJ\/mol}<br>]<\/p>\n\n\n\n<p>Thus, the enthalpy change for the decomposition of 2 moles of N\u2082O into nitrogen and oxygen is approximately <strong>+1668 kJ\/mol<\/strong>. Since the reaction is endothermic (energy is absorbed), the positive value indicates that the decomposition requires energy input to proceed.<\/p>\n\n\n\n<h3 class=\"wp-block-heading\">Conclusion:<\/h3>\n\n\n\n<p>The enthalpy change for the reaction is positive, meaning the decomposition of N\u2082O absorbs energy, making it an endothermic process.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Dinitrogen monoxide, N\u2082O, can decompose to nitrogen and oxygen gas:2 N2O(g) \u2192 2 N2(g) + O2(g)Use bond dissociation enthalpies (see Table on last page) to estimate the enthalpy change for this reaction. (Hint: As in problem #6, first draw the Lewis structures of the reactants and products that obey the octet rule so you knov [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[25],"tags":[],"class_list":["post-192976","post","type-post","status-publish","format-standard","hentry","category-exams-certification"],"_links":{"self":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts\/192976","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/comments?post=192976"}],"version-history":[{"count":0,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts\/192976\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/media?parent=192976"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/categories?post=192976"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/tags?post=192976"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}