{"id":196066,"date":"2025-03-02T09:02:18","date_gmt":"2025-03-02T09:02:18","guid":{"rendered":"https:\/\/learnexams.com\/blog\/?p=196066"},"modified":"2025-03-02T09:02:20","modified_gmt":"2025-03-02T09:02:20","slug":"draw-the-newman-projections-for-the-anti-and-gauche-forms-of-12-dibromoethane","status":"publish","type":"post","link":"https:\/\/www.learnexams.com\/blog\/2025\/03\/02\/draw-the-newman-projections-for-the-anti-and-gauche-forms-of-12-dibromoethane\/","title":{"rendered":"Draw the Newman projections for the anti and gauche forms of 1,2-dibromoethane"},"content":{"rendered":"\n<p>Draw the Newman projections for the anti and gauche forms of 1,2-dibromoethane. The molecule has a dipole moment of 1.0 D.<\/p>\n\n\n\n<p>a) Which form is responsible for the molecular dipole (gauche\/anti)?<\/p>\n\n\n\n<p>(b) Which conformation of 1,2-dibromoethane is present in the greatest amount at equilibrium (eclipsed\/gauche\/&#8230;<\/p>\n\n\n\n<p><mark style=\"background-color:rgba(0, 0, 0, 0)\" class=\"has-inline-color has-ast-global-color-6-color\"><strong>The Correct Answer and Explanation is :<\/strong><\/mark><\/p>\n\n\n\n<p><strong>a) Which form is responsible for the molecular dipole (gauche\/anti)?<\/strong><\/p>\n\n\n\n<p>The <strong>gauche<\/strong> conformation of 1,2-dibromoethane is responsible for the molecular dipole. In this conformation, the bromine atoms are positioned at a 60\u00b0 dihedral angle relative to each other, resulting in a net dipole moment because the individual bond dipoles do not cancel out. In contrast, the <strong>anti<\/strong> conformation, where the bromine atoms are 180\u00b0 apart, has a net dipole moment of zero due to the cancellation of opposing dipoles. \ue200cite\ue202turn0search11\ue201\ue206<\/p>\n\n\n\n<p><strong>b) Which conformation of 1,2-dibromoethane is present in the greatest amount at equilibrium (eclipsed\/gauche\/anti)? Provide the correct answer and a 300-word explanation.<\/strong><\/p>\n\n\n\n<p>At equilibrium, the <strong>anti<\/strong> conformation of 1,2-dibromoethane predominates. This preference arises from a combination of steric and electronic factors:\ue206<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li><strong>Steric Factors:<\/strong> In the anti conformation, the bulky bromine atoms are positioned opposite each other, minimizing steric repulsion. This arrangement reduces electron cloud overlap, leading to a more stable and lower-energy state.\ue206<\/li>\n\n\n\n<li><strong>Electronic Factors:<\/strong> The gauche conformation places the bromine atoms closer together (at a 60\u00b0 dihedral angle), resulting in increased electron-electron repulsion. This proximity raises the potential energy of the molecule, making the gauche form less stable.\ue206<\/li>\n<\/ul>\n\n\n\n<p>Experimental measurements support this theoretical understanding. The observed dipole moment of 1,2-dibromoethane is approximately 1.0 D, indicative of a significant population of the gauche conformer. However, the anti conformation remains the most stable and is present in the greatest amount at equilibrium. \ue200cite\ue202turn0search11\ue201\ue206<\/p>\n\n\n\n<p>In summary, while both anti and gauche conformations exist, the anti conformation is favored at equilibrium due to minimized steric and electronic repulsions, leading to greater stability.\ue206<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Draw the Newman projections for the anti and gauche forms of 1,2-dibromoethane. The molecule has a dipole moment of 1.0 D. a) Which form is responsible for the molecular dipole (gauche\/anti)? (b) Which conformation of 1,2-dibromoethane is present in the greatest amount at equilibrium (eclipsed\/gauche\/&#8230; The Correct Answer and Explanation is : a) Which form [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[25],"tags":[],"class_list":["post-196066","post","type-post","status-publish","format-standard","hentry","category-exams-certification"],"_links":{"self":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts\/196066","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/comments?post=196066"}],"version-history":[{"count":0,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts\/196066\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/media?parent=196066"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/categories?post=196066"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/tags?post=196066"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}