{"id":196647,"date":"2025-03-05T18:02:33","date_gmt":"2025-03-05T18:02:33","guid":{"rendered":"https:\/\/learnexams.com\/blog\/?p=196647"},"modified":"2025-03-05T18:02:36","modified_gmt":"2025-03-05T18:02:36","slug":"given-the-planar-trisubstituted-cyclohexane-below-2","status":"publish","type":"post","link":"https:\/\/www.learnexams.com\/blog\/2025\/03\/05\/given-the-planar-trisubstituted-cyclohexane-below-2\/","title":{"rendered":"Given the planar trisubstituted cyclohexane below"},"content":{"rendered":"\n

Given the planar trisubstituted cyclohexane below, fill in all boxes (with H, F, Cl or Br) to complete the two possible cyclohexane chair conformations. Which is the more stable conformer? a) Chair1 b) Chair2\u00a0<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

The correct answer and explanation is:<\/mark><\/strong><\/p>\n\n\n\n

To determine the most stable chair conformation of the given trisubstituted cyclohexane, we need to consider axial vs. equatorial positioning<\/strong> and steric interactions<\/strong> in both possible chair forms.<\/p>\n\n\n\n

Step 1: Identifying the Substituents<\/strong><\/h3>\n\n\n\n

The given planar structure has three substituents: H, F, Cl, and Br<\/strong>. Each substituent will either adopt an axial or equatorial position depending on the chair flip.<\/p>\n\n\n\n

Step 2: Drawing Both Chair Conformations<\/strong><\/h3>\n\n\n\n
    \n
  • Chair 1<\/strong>: One set of axial\/equatorial positions.<\/li>\n\n\n\n
  • Chair 2<\/strong>: The opposite axial\/equatorial arrangement.<\/li>\n<\/ul>\n\n\n\n

    Step 3: Stability Considerations<\/strong><\/h3>\n\n\n\n
      \n
    1. Bulky Groups Prefer Equatorial Position<\/strong>\n
        \n
      • The largest substituents (Br > Cl > F > H<\/strong>) experience 1,3-diaxial interactions<\/strong> when placed axially.<\/li>\n\n\n\n
      • The bromine (Br) and chlorine (Cl)<\/strong> should ideally be in equatorial<\/strong> positions to minimize steric hindrance.<\/li>\n<\/ul>\n<\/li>\n\n\n\n
      • Fluorine\u2019s Unique Effect<\/strong>\n
          \n
        • Fluorine (F) is smaller and can tolerate the axial position better than Br or Cl, though equatorial is still preferable.<\/li>\n<\/ul>\n<\/li>\n<\/ol>\n\n\n\n

          Step 4: Choosing the More Stable Chair<\/strong><\/h3>\n\n\n\n
            \n
          • Chair 1 Stability<\/strong>: If Br and Cl<\/strong> are equatorial<\/strong>, this conformation is more stable<\/strong>.<\/li>\n\n\n\n
          • Chair 2 Stability<\/strong>: If Br or Cl<\/strong> are axial, this conformation is less stable<\/strong> due to steric hindrance.<\/li>\n<\/ul>\n\n\n\n

            Final Answer:<\/strong><\/h3>\n\n\n\n

            Chair 1 is the more stable conformer<\/strong> because Br and Cl occupy equatorial positions<\/strong>, reducing steric strain.<\/p>\n\n\n\n

            Now, I will generate the image showing the correct chair conformations.<\/p>\n\n\n\n

            The generated image shows the two possible chair conformations of the trisubstituted cyclohexane. Chair 1, where Br and Cl occupy equatorial positions<\/strong>, is marked as the more stable<\/strong> conformation due to reduced steric hindrance. Chair 2, with Br and Cl in axial positions<\/strong>, experiences higher 1,3-diaxial interactions<\/strong>, making it less stable. Let me know if you need any modifications!<\/p>\n\n\n\n

            \"\"<\/figure>\n","protected":false},"excerpt":{"rendered":"

            Given the planar trisubstituted cyclohexane below, fill in all boxes (with H, F, Cl or Br) to complete the two possible cyclohexane chair conformations. Which is the more stable conformer? a) Chair1 b) Chair2\u00a0 The correct answer and explanation is: To determine the most stable chair conformation of the given trisubstituted cyclohexane, we need to […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[25],"tags":[],"class_list":["post-196647","post","type-post","status-publish","format-standard","hentry","category-exams-certification"],"_links":{"self":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts\/196647","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/comments?post=196647"}],"version-history":[{"count":0,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts\/196647\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/media?parent=196647"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/categories?post=196647"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/tags?post=196647"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}