{"id":233820,"date":"2025-06-13T12:43:21","date_gmt":"2025-06-13T12:43:21","guid":{"rendered":"https:\/\/learnexams.com\/blog\/?p=233820"},"modified":"2025-06-13T12:43:24","modified_gmt":"2025-06-13T12:43:24","slug":"ironiii-chloride-and-sodium-hydroxide","status":"publish","type":"post","link":"https:\/\/www.learnexams.com\/blog\/2025\/06\/13\/ironiii-chloride-and-sodium-hydroxide\/","title":{"rendered":"Iron(III) chloride and sodium hydroxide"},"content":{"rendered":"\n<p> Iron(III) chloride and sodium hydroxide: FeCl3 + NaOH \u00e2\u2020\u2019 Fe(OH)3 + NaCl Balanced Equation: FeCl3 + 3NaOH \u00e2\u2020\u2019 Fe(OH)3 + 3NaCl Total Ionic Equation: Fe3+ + 3Cl- + 3Na+ + 3OH- \u00e2\u2020\u2019 Fe(OH)3 + 3Na+ + 3Cl- Net Ionic Equation: Fe3+ + 3OH- \u00e2\u2020\u2019 Fe(OH)3 Spectator Ions: Na+ and Cl- Precipitate: Fe(OH)3 Magnesium sulfate and potassium phosphate (potassium produces a soluble compound): MgSO4 + K3PO4 \u00e2\u2020\u2019 Mg3(PO4)2 + K2SO4 Balanced Equation: 3MgSO4 + 2K3PO4 \u00e2\u2020\u2019 Mg3(PO4)2 + 3K2SO4 Total Ionic Equation: 3Mg2+ + 3SO4^2- + 2K+ + 3PO4^3- \u00e2\u2020\u2019 Mg3(PO4)2 + 2K+ + 3SO4^2- Net Ionic Equation: 3Mg2+ + 3SO4^2- + 3PO4^3- \u00e2\u2020\u2019 Mg3(PO4)2 Spectator Ions: K+ and SO4^2- Precipitate: Mg3(PO4)2<\/p>\n\n\n\n<p><strong><mark style=\"background-color:rgba(0, 0, 0, 0)\" class=\"has-inline-color has-ast-global-color-1-color\">The Correct Answer and Explanation is:<\/mark><\/strong><\/p>\n\n\n\n<h3 class=\"wp-block-heading\">Double Replacement Reactions: Precipitation and Ionic Equations<\/h3>\n\n\n\n<p>In aqueous chemistry, <strong>double replacement reactions<\/strong> often lead to the formation of an insoluble compound, or <strong>precipitate<\/strong>, which separates out of solution. Let&#8217;s analyze two such reactions step-by-step to determine the balanced equations, total and net ionic equations, and identify the spectator ions and the precipitate.<\/p>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h3 class=\"wp-block-heading\"><strong>Reaction 1: Iron(III) chloride and sodium hydroxide<\/strong><\/h3>\n\n\n\n<p><strong>Molecular Equation:<\/strong><\/p>\n\n\n\n<p>FeCl\u2083(aq) + 3NaOH(aq) \u2192 Fe(OH)\u2083(s) + 3NaCl(aq)<\/p>\n\n\n\n<p><strong>Balanced Equation:<\/strong><\/p>\n\n\n\n<p>This equation is already balanced. One Fe\u00b3\u207a ion reacts with three OH\u207b ions to form iron(III) hydroxide, a brown precipitate. Three Na\u207a ions balance the three Cl\u207b ions to form sodium chloride, which remains dissolved.<\/p>\n\n\n\n<p><strong>Total Ionic Equation:<\/strong><\/p>\n\n\n\n<p>Fe\u00b3\u207a(aq) + 3Cl\u207b(aq) + 3Na\u207a(aq) + 3OH\u207b(aq) \u2192 Fe(OH)\u2083(s) + 3Na\u207a(aq) + 3Cl\u207b(aq)<\/p>\n\n\n\n<p><strong>Net Ionic Equation:<\/strong><\/p>\n\n\n\n<p>Fe\u00b3\u207a(aq) + 3OH\u207b(aq) \u2192 Fe(OH)\u2083(s)<\/p>\n\n\n\n<p><strong>Spectator Ions:<\/strong><\/p>\n\n\n\n<p>Na\u207a and Cl\u207b are unchanged on both sides of the equation and do not participate in the reaction.<\/p>\n\n\n\n<p><strong>Precipitate:<\/strong><\/p>\n\n\n\n<p>Fe(OH)\u2083 \u2013 an insoluble brown solid.<\/p>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h3 class=\"wp-block-heading\"><strong>Reaction 2: Magnesium sulfate and potassium phosphate<\/strong><\/h3>\n\n\n\n<p><strong>Molecular Equation:<\/strong><\/p>\n\n\n\n<p>3MgSO\u2084(aq) + 2K\u2083PO\u2084(aq) \u2192 Mg\u2083(PO\u2084)\u2082(s) + 3K\u2082SO\u2084(aq)<\/p>\n\n\n\n<p><strong>Balanced Equation:<\/strong><\/p>\n\n\n\n<p>Three magnesium sulfate units provide 3 Mg\u00b2\u207a ions, and two potassium phosphate units provide 2 PO\u2084\u00b3\u207b ions. These combine to form magnesium phosphate, Mg\u2083(PO\u2084)\u2082, an insoluble solid. Potassium sulfate remains in solution.<\/p>\n\n\n\n<p><strong>Total Ionic Equation:<\/strong><\/p>\n\n\n\n<p>3Mg\u00b2\u207a(aq) + 3SO\u2084\u00b2\u207b(aq) + 6K\u207a(aq) + 2PO\u2084\u00b3\u207b(aq) \u2192 Mg\u2083(PO\u2084)\u2082(s) + 6K\u207a(aq) + 3SO\u2084\u00b2\u207b(aq)<\/p>\n\n\n\n<p><strong>Net Ionic Equation:<\/strong><\/p>\n\n\n\n<p>3Mg\u00b2\u207a(aq) + 2PO\u2084\u00b3\u207b(aq) \u2192 Mg\u2083(PO\u2084)\u2082(s)<\/p>\n\n\n\n<p><strong>Spectator Ions:<\/strong><\/p>\n\n\n\n<p>K\u207a and SO\u2084\u00b2\u207b are not involved in the actual precipitation.<\/p>\n\n\n\n<p><strong>Precipitate:<\/strong><\/p>\n\n\n\n<p>Mg\u2083(PO\u2084)\u2082 \u2013 a white solid precipitate.<\/p>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h3 class=\"wp-block-heading\">Conclusion:<\/h3>\n\n\n\n<p>In both reactions, an <strong>insoluble hydroxide or phosphate compound<\/strong> forms as a precipitate. The <strong>net ionic equations<\/strong> clearly show the actual chemical change, while <strong>spectator ions<\/strong> remain unchanged. Recognizing these patterns is fundamental in predicting reaction outcomes in aqueous solutions.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img decoding=\"async\" src=\"https:\/\/learnexams.com\/blog\/wp-content\/uploads\/2025\/06\/learnexams-banner8-338.jpeg\" alt=\"\" class=\"wp-image-233821\"\/><\/figure>\n","protected":false},"excerpt":{"rendered":"<p>Iron(III) chloride and sodium hydroxide: FeCl3 + NaOH \u00e2\u2020\u2019 Fe(OH)3 + NaCl Balanced Equation: FeCl3 + 3NaOH \u00e2\u2020\u2019 Fe(OH)3 + 3NaCl Total Ionic Equation: Fe3+ + 3Cl- + 3Na+ + 3OH- \u00e2\u2020\u2019 Fe(OH)3 + 3Na+ + 3Cl- Net Ionic Equation: Fe3+ + 3OH- \u00e2\u2020\u2019 Fe(OH)3 Spectator Ions: Na+ and Cl- Precipitate: Fe(OH)3 Magnesium sulfate and [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[25],"tags":[],"class_list":["post-233820","post","type-post","status-publish","format-standard","hentry","category-exams-certification"],"_links":{"self":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts\/233820","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/comments?post=233820"}],"version-history":[{"count":0,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts\/233820\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/media?parent=233820"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/categories?post=233820"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/tags?post=233820"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}