{"id":235290,"date":"2025-06-15T04:56:01","date_gmt":"2025-06-15T04:56:01","guid":{"rendered":"https:\/\/learnexams.com\/blog\/?p=235290"},"modified":"2025-06-15T04:56:04","modified_gmt":"2025-06-15T04:56:04","slug":"oh-5-p-toluenesulfonic-acid-pka-7-tsoh-oh-acetic-acid-pka-4-8","status":"publish","type":"post","link":"https:\/\/www.learnexams.com\/blog\/2025\/06\/15\/oh-5-p-toluenesulfonic-acid-pka-7-tsoh-oh-acetic-acid-pka-4-8\/","title":{"rendered":"~OH 5 p-toluenesulfonic acid pKa ~7 TsOH OH acetic acid pKa 4.8"},"content":{"rendered":"\n<p>~OH 5 p-toluenesulfonic acid pKa ~7 TsOH OH acetic acid pKa 4.8<\/p>\n\n\n\n<p><strong><mark style=\"background-color:rgba(0, 0, 0, 0)\" class=\"has-inline-color has-ast-global-color-1-color\">The Correct Answer and Explanation is:<\/mark><\/strong><\/p>\n\n\n\n<p><strong>Correct Answer: Acetic acid (pKa \u2248 4.8) is a stronger acid than p-toluenesulfonic acid (TsOH, pKa \u2248 7).<\/strong><\/p>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<p><strong>Explanation:<\/strong><\/p>\n\n\n\n<p>The pKa value of an acid measures its tendency to donate protons (H\u207a). A lower pKa value corresponds to a stronger acid because it indicates greater ease in losing a proton.<\/p>\n\n\n\n<p>Acetic acid, with a pKa of approximately 4.8, is more acidic than p-toluenesulfonic acid (TsOH), which has a pKa of about 7. This means acetic acid donates its proton more readily than TsOH does.<\/p>\n\n\n\n<p>Structurally, acetic acid contains a carboxylic acid group (-COOH), which can delocalize its negative charge after losing a proton through resonance with the adjacent carbonyl oxygen. This stabilization makes the conjugate base (acetate ion) relatively stable.<\/p>\n\n\n\n<p>In contrast, p-toluenesulfonic acid has a sulfonic acid group (-SO\u2083H), which is typically very strong. However, if the given pKa of TsOH is around 7 (unusually high, as TsOH normally has a pKa around -2), it would suggest the sulfonic acid group is less acidic in this context, possibly due to specific solvent conditions or experimental data provided.<\/p>\n\n\n\n<p>Under the provided data, the comparison of pKa values clearly shows that acetic acid (pKa 4.8) is the stronger acid than TsOH (pKa 7). This makes TsOH a weaker acid in this particular scenario, despite typical expectations.<\/p>\n\n\n\n<p>As a result, in an acid-base equilibrium, acetic acid would more likely donate a proton than TsOH, making the reaction favor formation of the conjugate base of acetic acid and the conjugate acid of TsOH. This principle is useful in understanding acid-base reactions, buffer systems, and reaction mechanisms in organic chemistry.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img decoding=\"async\" src=\"https:\/\/learnexams.com\/blog\/wp-content\/uploads\/2025\/06\/learnexams-banner5-578.jpeg\" alt=\"\" class=\"wp-image-235291\"\/><\/figure>\n","protected":false},"excerpt":{"rendered":"<p>~OH 5 p-toluenesulfonic acid pKa ~7 TsOH OH acetic acid pKa 4.8 The Correct Answer and Explanation is: Correct Answer: Acetic acid (pKa \u2248 4.8) is a stronger acid than p-toluenesulfonic acid (TsOH, pKa \u2248 7). Explanation: The pKa value of an acid measures its tendency to donate protons (H\u207a). A lower pKa value corresponds [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[25],"tags":[],"class_list":["post-235290","post","type-post","status-publish","format-standard","hentry","category-exams-certification"],"_links":{"self":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts\/235290","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/comments?post=235290"}],"version-history":[{"count":0,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts\/235290\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/media?parent=235290"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/categories?post=235290"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/tags?post=235290"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}