{"id":256816,"date":"2025-07-16T13:51:30","date_gmt":"2025-07-16T13:51:30","guid":{"rendered":"https:\/\/learnexams.com\/blog\/?p=256816"},"modified":"2025-07-16T13:51:33","modified_gmt":"2025-07-16T13:51:33","slug":"kinetics-and-equilibrium","status":"publish","type":"post","link":"https:\/\/www.learnexams.com\/blog\/2025\/07\/16\/kinetics-and-equilibrium\/","title":{"rendered":"KINETICS AND EQUILIBRIUM"},"content":{"rendered":"\n<p>KINETICS AND EQUILIBRIUM Writing the concentration equilibrium expression for heterogeneous equilibrium Write the concentration equilibrium constant expression for this reaction (aq) + H2O (aq) \u00e2\u2020\u2019 HF (aq) + H2O (l)<\/p>\n\n\n\n<p><strong><mark style=\"background-color:rgba(0, 0, 0, 0)\" class=\"has-inline-color has-ast-global-color-1-color\">The Correct Answer and Explanation is:<\/mark><\/strong><\/p>\n\n\n\n<p><strong>Correct answer:<\/strong><\/p>\n\n\n\n<p>The concentration equilibrium expression for the reaction is:<\/p>\n\n\n\n<p><strong>Kc = [HF] \/ [F\u207b]<\/strong><\/p>\n\n\n\n<p><strong>Explanation<\/strong><\/p>\n\n\n\n<p>In chemical equilibrium, the equilibrium constant expression (denoted as <strong>Kc<\/strong> when using concentrations) is derived from the balanced chemical equation. It represents the ratio of the concentrations of products to reactants, each raised to the power of their stoichiometric coefficients.<\/p>\n\n\n\n<p>In this case, the reaction is:<\/p>\n\n\n\n<p><strong>F\u207b (aq) + H\u2082O (l) \u21cc HF (aq) + OH\u207b (aq)<\/strong><\/p>\n\n\n\n<p>Note: It seems there was an issue in the question formatting. Since the original question shows HF and water on the right-hand side and &#8220;aq&#8221; on the left, this is most likely the fluoride ion reacting with water:<\/p>\n\n\n\n<p><strong>F\u207b (aq) + H\u2082O (l) \u21cc HF (aq) + OH\u207b (aq)<\/strong><\/p>\n\n\n\n<p>However, if the reaction given is:<\/p>\n\n\n\n<p><strong>F\u207b (aq) + H\u2082O (l) \u21cc HF (aq) + H\u2082O (l)<\/strong><\/p>\n\n\n\n<p>That would be chemically inconsistent, as water would not appear unchanged on both sides with HF formation. So, we assume the proper form is:<\/p>\n\n\n\n<p><strong>F\u207b (aq) + H\u2082O (l) \u21cc HF (aq) + OH\u207b (aq)<\/strong><\/p>\n\n\n\n<p>This is a <strong>heterogeneous equilibrium<\/strong> because water is a pure liquid. In equilibrium expressions, pure solids and pure liquids (like water in liquid form) are <strong>not included<\/strong> because their concentrations remain constant throughout the reaction.<\/p>\n\n\n\n<p>Therefore, the equilibrium expression is written as:<\/p>\n\n\n\n<p><strong>Kc = [HF][OH\u207b] \/ [F\u207b]<\/strong><\/p>\n\n\n\n<p>If the original reaction only involved F\u207b and water producing HF, as in:<\/p>\n\n\n\n<p><strong>F\u207b (aq) + H\u2082O (l) \u21cc HF (aq)<\/strong><\/p>\n\n\n\n<p>Then the equilibrium expression would simply be:<\/p>\n\n\n\n<p><strong>Kc = [HF] \/ [F\u207b]<\/strong><\/p>\n\n\n\n<p>This follows the same rule: exclude water since it is a liquid. The square brackets indicate molar concentration. This expression allows chemists to calculate or predict concentrations of species at equilibrium.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img decoding=\"async\" src=\"https:\/\/learnexams.com\/blog\/wp-content\/uploads\/2025\/07\/learnexams-banner9-179.jpeg\" alt=\"\" class=\"wp-image-256821\"\/><\/figure>\n","protected":false},"excerpt":{"rendered":"<p>KINETICS AND EQUILIBRIUM Writing the concentration equilibrium expression for heterogeneous equilibrium Write the concentration equilibrium constant expression for this reaction (aq) + H2O (aq) \u00e2\u2020\u2019 HF (aq) + H2O (l) The Correct Answer and Explanation is: Correct answer: The concentration equilibrium expression for the reaction is: Kc = [HF] \/ [F\u207b] Explanation In chemical equilibrium, [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[25],"tags":[],"class_list":["post-256816","post","type-post","status-publish","format-standard","hentry","category-exams-certification"],"_links":{"self":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts\/256816","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/comments?post=256816"}],"version-history":[{"count":0,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/posts\/256816\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/media?parent=256816"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/categories?post=256816"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.learnexams.com\/blog\/wp-json\/wp\/v2\/tags?post=256816"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}