Organic Chemistry Module 1 Exam

Organic Chemistry Module 1 Exam
1. The transition state geometry in an SN2 reaction is?
A) Trigonal planar.
B) Tetrahedral.
C) Pentagonal.
D) Trigonal bipyramidal.
E) Octahedral. - ✔✔D) Trigonal bipyramidal.
2. The nucleophile in an SN2 reaction approaches the alkyl halide from?
A) Anywhere, is does not matter.
B) The same side of the carbon atom that the halide atom is
attached to.
C) The backside of the carbon-halide bond.
D) The side of the carbon-halide bond.
E) The top of the carbon-halide bond. - ✔✔C) The backside of
the carbon-halide bond.
3. The strength of a nucleophile depends on several factors, which
statement is NOT true?
A) The anion is a stronger nucleophile than the neutral atom, or
molecule.
B) More polarizable atoms are better nucleophiles.
C) The degree of solvation affects the nucleophilicity.
D) The connection between nucleophilicity and basicity holds
across a row in the Periodic Table.
E) The connection between nucleophilicity and basicity holds
down a column in the Periodic Table. - ✔✔E) The
connection between nucleophilicity and basicity holds down
a column in the Periodic Table.
4. The order of carbocation stability is?
A) 1º > 2º > 3º

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